The photo, which was uploaded on Tuesday, has now received over 1.98 million 'likes', making it the most popular photo since the photo-sharing app was launched in 2010.
In the photo, newly married Kim and Kanye, both dressed to the nines and looking glamorous in Givenchy, are seen sharing their first kiss as a married couple.
The couple who are now enjoying their honeymoon in Ireland, married in a lavish ceremony in Italy last weekend, attended by celebrities like John Legend and Jaden Smith, as well as Kim's family including her mum, Kris Jenner and sisters Kendall Jenner and Khloe Kardashian.
Notably absent from the guests was her brother, Rob Kardashian, as was Kanye's 'Watch The Throne' collaborator Jay-Z and his wife Beyoncé.
The previous record was held by Justin Bieber and Selena Gomez, after Justin posted a photo five months ago, being hugged from behind by his on-and-off girlfriend Selena. The photo held the record with nearly 1.82 million likes.